Name: 
 

Ch 23 - Functional Groups - Section 3 and 4



Matching (Value 10)
 
 
Match each item with the correct statement below.
a.
functional group
f.
halogen
b.
hydroxyl group
g.
fatty acids
c.
carbonyl group
h.
alcohol
d.
carboxyl group
i.
glycerol
e.
ether
 

 1. 

a main component of fats and oils
 

 2. 

a carbon atom and an oxygen atom joined by a double bond
 

 3. 

a carbonyl group attached to a hydroxyl group
 

 4. 

a compound in which oxygen is bonded to two carbon atoms
 

 5. 

carboxylic acids with long hydrocarbon chains
 

 6. 

reacts with a carboxylic acid to form an ester
 
 
Match each item with the correct statement below.
a.
substitution reaction
d.
hydrogenation reaction
b.
addition reaction
e.
dehydrogenation reaction
c.
hydration reaction
 

 7. 

a reaction involving the loss of hydrogen
 

 8. 

a reaction in which an atom or group of atoms replaces another atom or group of atoms
 

 9. 

a reaction involving the addition of water to an alkene
 

 10. 

a reaction involving the addition of hydrogen to a carbon—carbon double bond to produce an alkane
 

Multiple Choice (Value 18)
Identify the choice that best completes the statement or answers the question.
 

 11. 

The IUPAC name for a carboxylic acid with two carbons in a straight chain would be ____.
a.
ethanalic acid
c.
ethanoic acid
b.
methacarboxylic acid
d.
dimethylmethanoic acid
 

 12. 

Which of the following compounds will produce the least energy when completely oxidized?
a.
hexanal
c.
hexanoic acid
b.
hexane
d.
hexanol
 

 13. 

Which carbon skeleton contains a carboxyl group?
a.

mc013-1.jpg
c.

C¾C¾C¾O
b.

mc013-2.jpg
d.

mc013-3.jpg
 

 14. 

Which of the following compounds is known as acetic acid?
a.

CHmc014-1.jpg—CHmc014-2.jpgOH
c.

mc014-4.jpg
b.

mc014-3.jpg
d.

mc014-5.jpg
 

 15. 

Aldehydes have the general structure ____________.
a.

mc015-1.jpg
c.

mc015-3.jpg
b.

mc015-2.jpg
d.

mc015-4.jpg
 

 16. 

Which carbon skeleton represents a ketone?
a.

mc016-1.jpg
c.

mc016-3.jpg
b.

mc016-2.jpg
d.

mc016-4.jpg
 

 17. 

Esters contribute which property to fruits?
a.
texture
c.
odor
b.
color
d.
skin thickness
 

 18. 

Based on your knowledge of intermolecular forces, which of the following would you expect to have the highest boiling point?
a.
hexanone
c.
hexanol
b.
hexane
d.
hexanal
 

 19. 

Which of the following carbon skeletons represents a carboxylic acid?
a.

mc019-1.jpg
c.

mc019-2.jpg
b.

C¾C¾C¾C¾C¾O
d.

mc019-3.jpg
 

 20. 

What is the name of the following compound?
mc020-1.jpg
a.
benzaldehyde
c.
phenylhyde
b.
cyclohexylhyde
d.
phenol aldehyde
 

 21. 

Which of the following compounds has the highest boiling point?
a.
2-pentanone
c.
pentane
b.
chloropentane
d.
pentene
 

 22. 

What is the name of the following compound?
mc022-1.jpg
a.
butanone
c.
butanal
b.
butanol
d.
butane
 

 23. 

What is the name of the following compound?
mc023-1.jpg
a.
4-butanone
c.
4-pentanone
b.
2-butanone
d.
2-pentanone
 

 24. 

What happens in a condensation reaction?
a.
cross-linking of monomers
b.
head-to-tail joining of monomers
c.
side-by-side joining of monomers
d.
substitution of a halogen on monomers
 

 25. 

Which of the following compounds is the most soluble in water?
a.
propanoic acid
c.
propanal
b.
propane
d.
l-bromopropane
 

 26. 

A ketone has the general structure ____________.
a.

R¾O¾R
c.

mc026-2.jpg
b.

mc026-1.jpg
d.

mc026-3.jpg
 

 27. 

What type of compound is the following?
mc027-1.jpg
a.
alcohol
c.
ketone
b.
ether
d.
aldehyde
 

 28. 

Which carbon skeleton represents an aldehyde?
a.

mc028-1.jpg
c.

mc028-3.jpg
b.

mc028-2.jpg
d.

none of the above
 

Short Answer: Complete 3 of the 4 below questions. (Value 6)
 

 29. 

Write the general structure for aldehyde compounds.
 

 30. 

Write the general structure for carboxylic acid compounds.
 

 31. 

Draw the structure of benzaldehyde.
 

 32. 

What is the expected product when the following compound is oxidized?
CHsa032-1.jpg¾CHsa032-2.jpg¾CHsa032-3.jpg¾CHsa032-4.jpgOH
 

Essay: (Value 6)
 

 33. 

Describe a polymerization condensation reaction. Give an example.
 

 34. 

Compare the properties of carboxylic acids with the properties of compounds with other functional groups.
 



 
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